Journal
ORGANIC LETTERS
Volume 3, Issue 18, Pages 2847-2850Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol010134x
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[GRAPHICS] The trifluoromethide ion generated in situ from TMSCF3 and TBAT (tetrabutylammonium triphenyldifluorosilicate), as well as TMAF (tetramethylammonium fluoride), adds to the alpha,beta -unsaturated hkert-butanesulfinimines exclusively in a 1,2 fashion with high diastereoselectivities, affording the first examples of chiral trifluoromethylated allylic amines.
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