Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 17, Pages 1638-1639Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b104964j
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Exceptionally high stereoselectivity (ee less than or equal to 98%, dr less than or equal to 99:1) in the cyclopropanation of alkenes with ethyl diazoacetate using a non-planar ruthenium(II) Schiff-base precatalyst is a result of eta C-2,O binding of the carbenoid ester intermediate, according to DFT calculations.
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