4.7 Article

NMR evidence of pentaoxo organosilicon complexes in dilute neutral aqueous silicate solutions

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 17, Pages 1564-1565

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b104713m

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Funding

  1. NCRR NIH HHS [RR01811] Funding Source: Medline
  2. NIGMS NIH HHS [GM-42208] Funding Source: Medline
  3. PHPPO CDC HHS [PHS 1 S10 RR 10444-01] Funding Source: Medline

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Silicon-29 NMR spectra of a neutral, dilute aqueous silicic acid solution, with a pH and Si concentration typical of soil solutions, reveal that a significant fraction of the silicon is incorporated in two five-coordinated organosilicon complexes when sodium gluconate is present.

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