Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 173, Issue 1-2, Pages 99-115Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S1381-1169(01)00147-9
Keywords
palladium nanoclusters; functional resins; catalysis; nanomorphology; accessibility
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The use of functional resins as designable supports for palladium nanoclusters is reviewed. Data are related to the generation of Pd nanoparticles under various conditions and inside gel-type or macroporous frameworks. The combination of different physico-chemical techniques (ISEC, ESR and PGSE NMR) is illustrated as a powerful tool for evaluating nanomorphology and molecular accessibility, mainly of gel-type resins. A few examples of catalytic applications are presented and discussed and prospects for wider utilizations are evaluated. (C) 2001 Elsevier Science B.V. All rights reserved.
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