Journal
ORGANIC LETTERS
Volume 3, Issue 19, Pages 3009-3012Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol016420q
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- NCRR NIH HHS [1S10-RR-04870] Funding Source: Medline
- NIGMS NIH HHS [GM 33328-18] Funding Source: Medline
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[GRAPHICS] The synthesis of (-)-epibatidine has been accomplished utilizing a highly exo-selective asymmetric hetero Diels-Alder reaction. The key steps employed to transform the resulting bicycle into the natural product include a fluoride-promoted fragmentation and a Hofmann rearrangement.
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