Journal
ORGANIC LETTERS
Volume 3, Issue 19, Pages 3001-3004Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol016379r
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[GRAPHICS] The reaction of lead(IV) 4-indolyl triacetate with substituted methyl 2-oxo-1-cyclohexanecarboxylates has been investigated as a route to the natural product N-methylwelsitindolinone C isothiocyanate. Reaction of lead(IV) reagent 18 with beta -ketoester 20 affords the desired coupled material in excellent yield and diastereoselectivity.
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