4.4 Article

Rhodium-catalyzed decomposition of indole-substituted α-diazo-β-keto esters:: three different reactions based on indole oxidation state

Journal

TETRAHEDRON LETTERS
Volume 42, Issue 39, Pages 6835-6838

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)01431-9

Keywords

rhodium(II)-catalyzed reactions of diazo esters; cyclopropanation of indole double bond; oxindole reaction with carbenoids; oxidation of indoline to indole using carbenoid

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Rhodium(II)-catalyzed decomposition of three indole-substituted alpha -diazo-beta -keto esters affords three different types of intramolecular reactions based on the oxidation state of the indole. (C) 2001 Published by Elsevier Science Ltd.

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