Journal
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume 148, Issue 10, Pages A1179-A1184Publisher
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.1403731
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The present work deals with the voltammetric and electrogravimetric behavior of Ni(OH)(2) electrodes in alkaline solutions and the effect of some additives, such as Co2+, Cd2+, and Zn2+, in the active material. The electrochemical behavior of the alpha or beta phases with the incorporation of the additives is analyzed by use of the electrochemical quartz crystal microbalance. Only Zn2+ as additive leads to the complete stabilization of the a phase avoiding, since the first cycle, the insertion of alkaline cations from the electrolyte. In all other alpha phases, the electroneutralization of charge is achieved by a small but representative participation of cations. In the case of beta electrodes, protons are the responsible for charge compensation, the cations movement being negligible. (C) 2001 The Electrochemical Society.
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