Journal
ELECTROCHEMISTRY COMMUNICATIONS
Volume 3, Issue 10, Pages 553-556Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/S1388-2481(01)00217-X
Keywords
sonochemical; vanadyl phosphate dihydrate; lithium battery; cathode; high energy density
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We report on a high energy density VOPO4. 2H(2)O cathode material prepared by the sonochemical method. VOPO4. 2H(2)O is rapidly prepared within 15 min by ultrasonic irradiation of an aqueous solution containing V2O5 and H3PO4. The sonochemically synthesized VOPO4. 2H(2)O forms rectangular polycrystals 1-3 tm in size as observed by transmission electron microscopy (TEM) and selected area electron diffraction. X-ray diffraction (XRD) and Fourier transformed infrared (FTIR) spectroscopic studies confirmed the phase purity. The electrochemical test of the sonochemically synthesized VOPO4. 2H(2)O in a nonaqueous Li salt electrolyte showed a cell voltage of 3.6 V and an energy density of 486 Wh/kg, along with a good reversibility for lithium insertion/extraction. (C) 2001 Elsevier Science B.V. All rights reserved.
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