Journal
BIOORGANIC CHEMISTRY
Volume 29, Issue 5, Pages 321-331Publisher
ACADEMIC PRESS INC
DOI: 10.1006/bioo.2001.1215
Keywords
steroid oxidation; metal coordination; cytochrome P450; enzyme mimics
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A manganese porphyrin having four 2,2'-bipyridyl groups on its meso positions was synthesized. In the presence of Cu2+ ions it catalyzes the regioselective oxidation of steroid substrates carrying auxiliary metal coordinating goups. (C) 2001 Academic Press.
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