Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 4, Issue 10, Pages 551-554Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S1387-7003(01)00263-5
Keywords
crystal structure; tris(vanadyl)-substituted tungstobismutate(III); alpha-B tungstobismutate; V/W/Bi-mixed polyanion
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The tris(vanadyl)-substituted tungstobismutate (III) [(VO)(3)(BiW9O33)(2)](12-) anion has been synthesized by reaction of alpha -B[BiW9O33](9-) with VOSO4 in aqueous solution. The anion is made of two alpha -B[BiW9O33](9-) units linked by a belt of three exterior VO2+ groups into an assembly of virtual D-3h symmetry. The three vanadium centers are well separated by a V . . .V distance of 5.375(4)-5.474(4) Angstrom. (C) 2001 Elsevier Science B.V. All rights reserved.
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