Journal
ORGANIC LETTERS
Volume 3, Issue 20, Pages 3225-3228Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0165692
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GRAPHICS The first enantioselective ruthenium olefin metathesis catalysts have been prepared, and high enantiomeric excesses (up to 90%) are observed in the desymmetrization of achiral trienes. A model consistent with the stereochemical outcome of the reactions is described and suggests side-on olefin binding and reorganization of the halide ligands.
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