Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 66, Issue 20, Pages 6505-6512Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo001775t
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Funding
- NCRR NIH HHS [RR 10524] Funding Source: Medline
- NIGMS NIH HHS [GM 59245] Funding Source: Medline
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The synthesis and fluorescent properties of a second generation. cooperative chemical sensor are described. The sensor has two interacting binding pockets for cooperative recognition of two analytes. Cooperative binding activates a ratiometric fluorescent response via formation of an excimer. Binding was characterized by NAM, absorption, and fluorescence spectroscopy. The advantages of separating the recognition elements from the fluorescent response elements are discussed.
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