Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 66, Issue 20, Pages 6595-6603Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo015617t
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- NCI NIH HHS [CA85641] Funding Source: Medline
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Rh-2(S-DOSP)(4)-catalyzed decomposition of heteroaryldiazoacetates in the presence of styrene results in highly diastereoselective and enantioselective cyclopropanations. Heteroaryldiazoacetates containing both electron-rich and electron-deficient heterocycles, such as thiophene, furan, pyridine, indole, oxazole, isoxazole, and benzoxazole, are effective in this chemistry. These studies broaden the range of diazo compounds containing both electron-withdrawing and electron-donating groups, which undergo highly diastereoselective cyclopropanations.
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