Journal
CATALYSIS TODAY
Volume 70, Issue 1-3, Pages 83-90Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S0920-5861(01)00409-6
Keywords
basicity; IR-probe molecules; MgO; acetylenes
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Methylacetylene (MA) and tert-butylacetylene (TA) were used as probe molecules in infra-red spectroscopy for characterisation of the basicity of MgO. Reference experiments with SiO2 showed the formation of a pi -complex via the C equivalent toC bond of MA or TA with the weakly acidic silanol groups. The adsorption model proposed for MA and TA on MgO involves a H-bonding adsorption interaction of the probe molecule via the acidic equivalent to CH end with the basic O2- sites with a possible simultaneous interaction of the C equivalent toC bond with OH groups which are preferentially located at corners on the MgO surface. (C) 2001 Elsevier Science BN. All rights reserved.
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