Journal
ORGANIC LETTERS
Volume 3, Issue 21, Pages 3393-3396Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol016617i
Keywords
-
Categories
Funding
- NIGMS NIH HHS [GM 43854] Funding Source: Medline
Ask authors/readers for more resources
[GRAPHICS] Both an intramolecular aglycon delivery (IAD) method and an intermolecular S(N)2 displacement method were examined for beta -selective glycosylations of cholesterol with D-mycosamine. An anomeric sulfoxide, sulfide, selenide, and fluoride were all successfully used as glycosyl donors in IAD reactions. The alpha -bromo ketone 19 was synthesized from protected mycosamine and employed in an intermolecular S(N)2 glycosylation reaction, Both routes were successful for the model alcohol, cholesterol.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available