Journal
SURFACE SCIENCE
Volume 492, Issue 3, Pages 285-293Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S0039-6028(01)01476-5
Keywords
photoelectron diffraction; surface structure, morphology, roughness, and topography; copper; aromatics; carboxylic acid; single crystal surfaces
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The local adsorption site and molecular orientation of the benzoate species adsorbed on Cu(1 1 0) at 330 K have been determined using Ols scanned-energy mode photoelectron diffraction, The molecule was found to interact with the surface via the carboxylate group, giving a Cu-O bond length of 1.91 A. The molecules occupy the short bridge sites (the O atoms being slightly displaced from atop sites) and are aligned along the [(1) over bar 1 0] azimuth with the molecular plane oriented perpendicular to the surface. (C) 2001 Elsevier Science B.V. All rights reserved.
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