4.4 Article

An oxidation of alcohols by oxygen with the enzyme laccase and mediation by TEMPO

Journal

TETRAHEDRON LETTERS
Volume 42, Issue 43, Pages 7551-7553

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)01463-0

Keywords

laccase; TEMPO; oxidation; alcohols; mediation

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A simple and efficient oxidation of alcohols to carbonyl compounds by oxygen at room temperature is described; it requires the laccase/TEMPO mediator system as the catalyst. A possible mechanistic explanation is provided. (C) 2001 Elsevier Science Ltd. All rights reserved.

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