4.5 Article

On the thermal stability of some ammonium salts

Journal

THERMOCHIMICA ACTA
Volume 378, Issue 1-2, Pages 107-112

Publisher

ELSEVIER
DOI: 10.1016/S0040-6031(01)00585-8

Keywords

kinetics of decomposition of ammonium salts; eyring parameters; kinetic parameters; ammonium acetate; ammonium nitrate; ammonium chloride

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The thermal behavior of ammonium acetate, nitrate and chloride were investigated. The dependences between Eyring parameters for particular salts were determined. The dependence of Gibbs free energy of activation on decomposition temperature was calculated. The values of maximum of transformation rate were compared with energies of chemical bonds between ions. (C) 2001 Elsevier Science B.V. All rights reserved.

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