4.6 Article Proceedings Paper

Flow injection-electrothermal atomic absorption spectrometry configurations: recent developments and trends

Journal

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
Volume 56, Issue 10, Pages 1801-1829

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0584-8547(01)00338-X

Keywords

flow injection; electrothermal atomic absorption spectrometry; sample pre-treatment; automated analysis

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This review aims to provide an account of the state-of-the-art, of recently introduced techniques and of future possibilities offered by flow analysis in order to automate sample pretreatment for electrothermal atomic absorption spectrometry (ETAAS). Topics such as on-line solid-liquid extraction, precipitation, coprecipitation, on-wall retention, solvent extraction and chemical vapor generation processes are used to illustrate the versatility of coupling flow injection (Fl) for analyte separation and preconcentration in the flow system or in the atomizer, The use of FI to make the introduction of slurries and highly viscous samples easier is considered as well as on-line microwave sample digestion. (C) 2001 Elsevier Science B.V. All rights reserved.

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