Journal
SYNTHESIS-STUTTGART
Volume -, Issue 15, Pages 2247-2254Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2001-18436
Keywords
Montmorillonite K-10; 4-phenylneoflavonoids; Fries rearrangement
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A new approach to synthesis of neoflavonoids, based on a high yielding Montmorillonite K-10 catalyzed lactone ring forming cyclization process, is described. The utility of this methodology is exemplified by its employment in the preparation of the substituted 4-phenylneoflavonoids 1-8. The free radical scavenging properties of these substances were evaluated. The neoflavonoids 1 and 5, which mimic esculetin-type antioxidants, were observed to quench hydrazyl free radicals.
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