Journal
MONATSHEFTE FUR CHEMIE
Volume 132, Issue 11, Pages 1237-1268Publisher
SPRINGER WIEN
DOI: 10.1007/s007060170016
Keywords
ionic solvation; nonaqueous solutions; mixed solvents; preferential solvation; preferential solvation quotient
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The history of studies on ionic solvation is briefly reviewed, and structural and dynamic properties of solvated ions in aqueous and nonaqueous solutions are discussed. An emphasis is placed on ionic solvation in nonaqueous mixed solvents in which preferential solvation of ions takes place. A new parameter for expressing the degree of preferential solvation of an ion is proposed.
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