Journal
ASTRONOMY & ASTROPHYSICS
Volume 379, Issue 2, Pages 588-591Publisher
EDP SCIENCES S A
DOI: 10.1051/0004-6361:20011332
Keywords
methods : laboratory; ISM : molecules; infrared : ISM : lines and bands
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The nu (3) feature of the OCN- ion near 2160 cm(-1) which is produced by acid-base reactions in cryogenic HNCO/NH3 samples shows a small matrix induced deuterium shift. A similar shift is found for the XCN band near this position produced by photolysis of CO/NH3 ice. This agreement, together with the abundant evidence already in the literature, clearly demonstrates that the XCN feature can be assigned to OCN-.
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