Journal
RUSSIAN CHEMICAL BULLETIN
Volume 50, Issue 11, Pages 2095-2100Publisher
SPRINGER
DOI: 10.1023/A:1015093100084
Keywords
E,E-1,4-diiodobuta-1,3-diene; alkynes; phosphines; phosphonates; palladium and nickel complexes; catalysis
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E,E-1,4-Diiodobuta-1,3-diene can enter into cross-coupling reactions with carbon- or other element-centered nucleophiles in the presence of Pd or Ni complexes as catalysts. Convenient procedures were developed for the stereoselective synthesis of E,E-1,4-dialkenylbuta-1,3-dienes, dienyl-1,4-bisphosphonates, E,E-1,4-bis(diphenylphosphino)buta-1,3-diene, E,E-1,4-diphenylbuta-1,3-diene, and E,E-1,4-bis(thiophenyl)buta-1,3-diene.
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