Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 105, Issue 43, Pages 10659-10668Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp012160i
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The reaction of superoxide with carbon dioxide is studied using voltammetry and potential step chronoamperometry at polycrystalline gold disk microelectrodes in a DMSO electrolyte. In agreement with prior work, it is found that a reaction occurs between the superoxide anion radical and carbon dioxide, effectively precluding their simultaneous detection at low levels of carbon dioxide. The reaction rate is found to be first-order with respect to both carbon dioxide and superoxide, consistent with an ECE or DISP1 type process. A rate constant is determined for this reaction based Upon two independent methods: fast scan cyclic voltammetric measurements and steady-state voltammetric signals. These methods yield a consistent rate constant of 3.7 +/- 1.6 x 10(5) M-1 s(-1). Potential step chronoamperometric measurements reveal that oxygen adsorbs onto a gold electrode surface, to form a monolayer both in the presence and absence of carbon dioxide. A rate constant for the reduction of surface-bound oxygen to superoxide is reported.
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