Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 66, Issue 22, Pages 7443-7448Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo010623a
Keywords
-
Categories
Ask authors/readers for more resources
The total synthesis of asteriscanolide (1) has been achieved by taking advantage on an intermolecular Pauson-Khand cycloaddition and a ring-closing metathesis as key bond-forming transformations. The approach incorporates the cyclooctane stereogenic center prior to ring formation. Interestingly, the ring-closing metathesis generates a new eight-membered ring with an in-out intrabridgehead relationship.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available