4.4 Article

First syntheses of 1,13-and 1,15-dihydroxyherbertenes, and herbertenolide by applying intramolecular Heck reaction for the construction of adjacent quaternary centers

Journal

TETRAHEDRON
Volume 57, Issue 45, Pages 9299-9307

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(01)00932-2

Keywords

1,13-dihydroxyherbertene; 1,15-dihydroxyherbertene; herbertenolide; herbertane-type sesquiterpene; Heck reaction; palladium

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1,13- and 1,15-Dihydroxyherbertenes and hebertenolide, typical herbertane-type sesquiterpenes with an oxidized methyl group, were synthesized by using intramolecular Heck reaction for the construction of adjacent quaternary centers. (C) 2001 Elsevier Science Ltd. All rights reserved.

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