Journal
MACROMOLECULES
Volume 34, Issue 23, Pages 8354-8360Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma010746x
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The coexistence of two different conformational states in one molecule has been visualized by scanning force microscopy for a rod-globule transition of brush molecules adsorbed on a water surface. The transition, which occurred upon lateral compression of monolayers, was also examined theoretically by scaling analysis that proved its first-order character. The transition becomes less distinct with decreasing length of the side chains and finally vanishes below a certain critical value.
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