Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 105, Issue 44, Pages 10826-10830Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp011455t
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A thin film formed by an amphiphilic catenane is shown to exhibit bistable behavior. The film is grown by self-assembly from two different solutions onto a mica surface. Self-recognition of the solute molecules by the first monolayer of the adsorbed molecules drives the switch between two co-conformations, characterized by different polar character, which are nearly degenerate once deposited on the surface. The phenomenon takes the form of a wetting/dewetting transition and propagates the intramolecular change to the mesoscopic scale.
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