Journal
TETRAHEDRON LETTERS
Volume 42, Issue 47, Pages 8333-8336Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)01789-0
Keywords
asymmetric catalysis; Ti(salen); di-mu-oxo Ti(salen); sulfoxidation; cis-beta structure; non-linear effect
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Asymmetric sulfoxidation using di-mu -oxo Ti(salen) complex 2 as the catalyst was revealed to proceed through C-2-symmetric Ti(salen) complex 6 and peroxo Ti(salen) complex 4 in sequence on the basis of MS and NMR studies of the complexes and the observation of positive non-linear effect. (C) 2001 Elsevier Science Ltd. All rights reserved.
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