Journal
ORGANOMETALLICS
Volume 20, Issue 24, Pages 5245-5247Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om010644v
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The combination of L-prolinamide with (p-CymeneRuCl(2))(2) or (Cp*RhCl2)(2) in the presence of KOH/2-propanol, has been found to generate catalysts in situ that are capable of enantioselectively reducing aryl ketones to the respective (R)-alcohols. Furthermore, when the catalyst derived from (p-CymeneRuCl(2))(2)/L-prolinamide was applied to the asymmetric reduction of 1'-tetralone at -24 degreesC, (R)-tetralol was produced in 93% ee.
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