Journal
ORGANOMETALLICS
Volume 20, Issue 24, Pages 4993-4995Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om010575k
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A uranium silyl compound, (Ar[Bu-t]N)(3)USi-(SiMe3)(3) (1; Ar = 3,5-C6H3Me2), has been synthesized, isolated, and characterized structurally and theoretically; compound 1 crystallizes in the space group P < (3)over bar > and its U-Si interatomic distance was found to be 3.091(3) Angstrom. Geometry optimizations were carried out for the model systems H3EU(NH2)(3) (E = C, Si, Ge, Sn) with a set of reasonable constraints; calculated U-E distances and bond energies are in good accord with experimental data.
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