Journal
ORGANIC LETTERS
Volume 3, Issue 24, Pages 3955-3957Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol016848p
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[GRAPHICS] Vinylsilanes are converted into enamides by a sequence comprising epoxidation, nucleophilic ring opening of the resulting epoxysilanes with NaN3, and reduction of the azide, followed by a one-pot N-acylation/Peterson elimination process. This method is distinguished by its wide applicability and stereoselective course.
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