Journal
PROGRESS IN POLYMER SCIENCE
Volume 26, Issue 10, Pages 2083-2134Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0079-6700(01)00033-8
Keywords
aqueous solution; suspension; emulsion; miniemulsion; nitroxide; atom transfer radical polymerization; reversible transfer; reversible addition-fragmentation transfer
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Controlled/living radical polymerizations carried out in the presence of water have been examined. These aqueous systems include both the homogeneous solutions and the various heterogeneous media, namely dispersion, suspension, emulsion and miniemulsion. Among them, the most common methods allowing control of the radical polymerization, such as nitroxide-mediated polymerization, atom transfer radical polymerization and reversible transfer, are presented in detail. (C) 2001 Elsevier Science Ltd. All rights reserved.
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