Journal
CURRENT OPINION IN BIOTECHNOLOGY
Volume 12, Issue 6, Pages 564-573Publisher
ELSEVIER SCI LTD
DOI: 10.1016/S0958-1669(01)00264-6
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Aromatic dioxygenases have been found to catalyse single and tandem oxidation reactions of conjugated polyenes. Rational selection and design of dioxygenases, allied to substrate shape, size and substitution pattern, has been used to control regiochemistry and stereochemistry during the oxygenation process. The resulting enantiopure bioproducts have been increasingly utilised as precursors for new and alternative routes in chiral synthesis.
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