Journal
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Volume 145, Issue 3, Pages 183-194Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S1010-6030(01)00581-0
Keywords
laser ablation; titanium nitride; ultrafast microscopy
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The fundamental mechanisms of photothermal laser ablation of thin films of refractory materials on glass are investigated, using time-resolved microscopy with variable duration ablation pulses (1 ns-10 mus). A fundamental understanding of ablation mechanisms can be used to develop designer materials with ultra efficient ablation, i.e. materials that can be ablated using economical low power laser sources. Refractory Ti and TiN thin film coatings on glass substrates were studied, with the intent of finding materials that can store and then suddenly release a great deal of thermoelastic stress energy that is produced by heating with relatively low intensity laser pulses. Threshold fluences as low as J(th) approximate to 50 mJ/cm(2) were realized. Time-resolved microscopy shows that brittle TiN coatings ablate by violent cracking on all time scales. Similar behavior is observed for Ti, at 1 ns and 110 ns, but at 10 mus the Ti melts but does not ablate. A thermal conduction model is used to show that the temperatures in the coatings at ablation threshold are a factor of 2 (Ti) or 3 (TiN) below the melting point. Calculations of the thermoelastic stress in the coatings shows that stress-assisted ablation occurs when the stored stress energy exceeds the coating adhesion to the substrate by about one order of magnitude. The photothermal stress energy in the coating can be converted almost completely into kinetic energy of the ablated material. (C) 2001 Elsevier Science B.V. All rights reserved.
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