Journal
TETRAHEDRON LETTERS
Volume 42, Issue 49, Pages 8709-8711Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)01885-8
Keywords
cyclisation; lactones; natural products; terpenes and terpenoids
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A synthetic route to an unnatural diastereoisomer of colombiasin A is described. Key features are an arene alkylation with a gamma -methylene-gamma -butyrolactone and an intramolecular Diels-Alder cycloaddition. (C) 2001 Elsevier Science Ltd. All rights reserved.
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