Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 637, Issue -, Pages 251-257Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-328X(01)00912-3
Keywords
ferromagnetism; organic radical; ferrocene; ESR
Categories
Ask authors/readers for more resources
A polychlorotriphenylmethyl diradical connected by a 1,1'-ferrocenylendivinylene bridge has been synthesized and characterized. ESR frozen solution experiments down to helium temperature showed that the organometallic unit acts as a ferromagnetic coupler. This fact was supported by ZINDO/1 semiempirical calculations, which showed that the two singly occupied molecular orbitals (SOMOs) are non disjoint in addition to be almost degenerated. (C) 2001 Elsevier Science BN. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available