Journal
TETRAHEDRON LETTERS
Volume 42, Issue 49, Pages 8737-8740Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)01895-0
Keywords
asymmetric activation; asymmetric hydrogenation; monodentate phosphites; biphenyl ligands; rhodium catalysts
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A new method is presented with which achiral, conformationally flexible biphenylphosphites can be activated by easily available chiral alcohols to give monodentate phosphite ligands that are effective in rhodium-catalysed enantio selective hydrogenation. (C) 2001 Elsevier Science Ltd. All rights reserved.
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