Journal
CHEMISTRY LETTERS
Volume -, Issue 12, Pages 1216-1217Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2001.1216
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The boron-metal exchange reaction of (arylsilyl)boranes with alkyllithiums, potassium tert-butoxide, and methylmagnesium. bromide affords the corresponding silyllithium, silylpotassium, and silylmagnesium compounds, respectively. Especially, the boron-lithium exchange reaction occurs even in hydrocarbon solvents such as toluene and hexane as well as in THF.
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