Journal
JOURNAL OF CATALYSIS
Volume 204, Issue 2, Pages 520-524Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1006/jcat.2001.3396
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In a recent paper (J.A. Dumesic, J. Catal. 185, 496 (1999)), Dumesic argued that DeDonder relations offer a rigorous approach for assessing whether a reaction scheme contains a rate deter-mining step, Here, we argue that, while analysis with DeDonder relations is a very powerful approach that has many advantages, it has a limitation with respect to finding the rate determining step, and another method, previously proposed by this author (C.T. Campbell, Topics Catal. 1, 353 (1994)) involving the degree of rate control, is preferable in that particular respect. An approach for extending this latter method to transient kinetic conditions is also suggested. (C) 2001 Elsevier Science.
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