Journal
CHEMISTRY LETTERS
Volume -, Issue 1, Pages 26-27Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2002.26
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Highly efficient, direct, and enantioselective synthesis of useful chiral building blocks with excellent ee was performed by the catalytic asymmetric acylation of ineso-1,3-propanediols. A structurally most simple meso-1,3-propanediol, 2-methyl-1,3-propanediol, was asymmetrized in 96% ee catalyzed by 0.5 mol% of chiral 1,2-diamine.
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