Journal
ORGANIC LETTERS
Volume 4, Issue 1, Pages 83-86Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol016946a
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GRAPHICS 2-Vinyloxiranes have been found to be excellent surrogates to beta,gamma-unsaturated aldehydes. These valuable electrophiles, generated in situ by treatment of a 2-vinyloxirane with a catalytic amount of Sc(OTf)(3), are effectively trapped by the chiral allylating agents based on alpha-pinene, affording bishomoallylic alcohols in high yield and excellent selectivity.
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