Journal
SCIENCE
Volume 295, Issue 5553, Pages 305-308Publisher
AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/science.1067074
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Funding
- NIGMS NIH HHS [R01 GM63188-01] Funding Source: Medline
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Arylboron compounds have intriguing properties and are important building blocks for chemical synthesis. A family of Ir catalysts now enables the direct synthesis of arylboron compounds from aromatic hydrocarbons and boranes under solventless conditions. The Ir catalysts are highly selective for C-H activation and do not interfere with subsequent in situ transformations, including Pd-mediated cross-couplings with aryl halides. By virtue of their favorable activities and exceptional selectivities, these Ir catalysts impart the synthetic versatility of arylboron reagents to C-H bonds in aromatic and heteroaromatic hydrocarbons.
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