Journal
TETRAHEDRON LETTERS
Volume 43, Issue 3, Pages 355-358Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)02177-3
Keywords
alpha-siloxyamide; alpha-hydroxyamide; carbamoylsilane
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The reaction of a carbamoylsilane with aldehydes or ketones affords alpha-siloxyamides. The addition reaction is catalyzed by fluoride ion (TBAT, 25-50degreesC), but proceeds in the absence of catalyst at higher temperatures (50-100degreesC). (C) 2002 Elsevier Science Ltd. All rights reserved.
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