Journal
TETRAHEDRON LETTERS
Volume 43, Issue 3, Pages 363-365Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)02142-6
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Double binding of a steroid substrate to our previously described mimic of the cytochrome P-450 enzymes hydroxylates carbon 9 of the steroid, but with a second significant product. The geometry has been adjusted with new catalysts that show high selectivity and excellent turnover for the C-9 hydroxylation. (C) 2002 Elsevier Science Ltd. All rights reserved.
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