Journal
ORGANOMETALLICS
Volume 21, Issue 2, Pages 253-255Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om010874+
Keywords
-
Categories
Ask authors/readers for more resources
Well-defined 16-electron metal amido complexes bearing chiral Ts-diamine ligands readily react with nitromethane, acetone, or phenylacetylene to give new organometallic compounds in almost quantitative yields. For example, an Ir amido complex, [(R,R)-Tscydn], reacts with nitromethane at room temperature to give quantitatively a nitromethyl Ir complex, Cp*Ir-(CH2NO2)[(R,R)-Tscydn], as a single diastereomer. The isolable organometallic compounds with chiral amine ligands are relevant to active catalysts for asymmetric C-C bond formation.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available