4.4 Article

Sc(OTf)3-catalyzed acetolysis of 1,6-anhydro-β-hexopyranoses and solvent-free per-acetylation of hexoses

Journal

TETRAHEDRON LETTERS
Volume 43, Issue 5, Pages 851-855

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)02253-5

Keywords

acetolysis; acetylation; Sc(OTf)(3); carbohydrates

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Acetolysis of 1,6-anhydro-beta-hexopyranoses and solvent-free per-acetylation of hexoses with acetic anhydride at roots temperature in excellent yields employing 0.5 mol% scandium(III) trifluoromethanesulfonate as an extremely efficient catalyst are, respectively, described here. (C) 2002 Elsevier Science Ltd. All rights reserved.

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