Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 113, Issue 1, Pages 101-103Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-1139(01)00502-4
Keywords
2,3,3,4,4,5,5-heptafluoro-1-trifluoromethyl-1,2-epoxycyclopentane; 2-isopropyl-acetophenone imine; intramolecular rearrangement; 4,4,5,5,6,6,7,8,8,8-decafluoro-1-isopropylamino-1-phenyl-oct-1-en-3-one
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2,3,3,4,4,5,5-Heptafluoro-1-trifluoromethyl-1,2-epoxycyclopentane reacted with 2-isopropyl-acetophenone imine giving 2,3,3,4,4,5,5-heptafluoro-2-trifluoromethyl-1-(2'-isopropylimino-2'-phenylethane) cyclopentan-1-ol, which in its turn underwent an intramolecular rearrangement yielding the linear 4,4,5,5,6,6,7,8,8,8-decafluoro-1-isopropylamino-oct-1-en-3-one, being characterized by X-ray structural analysis (triclinic, P-1, a = 920.5(2), b = 1027.9(3), c = 1127.4(3) pm, alpha = 110.99, beta = 105.68degrees, gamma = 96.75degrees). (C) 2002 Elsevier Science B.V. All rights reserved.
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