Journal
INORGANICA CHIMICA ACTA
Volume 328, Issue -, Pages 39-44Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0020-1693(01)00659-4
Keywords
Heck reaction; P-S hybrid ligands; palladium complexes; catalysis
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The novel palladium phosphino-thioether P-S chelate complex, [PdCl2{MeSC6H4-2-(CH2PPh2)}] (3) is a highly efficient catalyst for the olefinic coupling of aryl bromo and iodo compounds to olefins under aerobic conditions, leading to more than 10(6) turnovers for the reactions with bromo and iodo benzenes. (C) 2002 Elsevier Science B.V. All rights reserved.
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